Product ID:08610KUZ-GD ALIPHATIC POLYISOCYANATE #37030 BLACK ZENTHANE
MSDS Date:08/02/1996
FSC:8010
NIIN:01-229-7542
MSDS Number: CDVSN

HENTZEN COATINGS INC

6937 W MILL ROAD
MILWAUKEE, WI 53218-1225
US

Emergency Phone: 414-353-4200 800-424-9300(CHEMTREC)

Info Phone: 414-353-4200

Preparer: JANE FREEMAN

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

METHYL ISOAMYL KETONE SOLVENT

CAS: 110-12-3

RTECS: MP3850000

Fraction By Weight: 24.713%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

BLACK IRON OXIDE PIGMENT

CAS: 1317-61-9

Fraction By Weight: 5-10%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

SILICA PIGMENT (SARA 313)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 20-30%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI)(EXACT

CAS: 28182-81-2

RTECS: HQ9170000

Fraction By Weight: 20-30%

AROMATIC HYDROCARBONS (MIXTURE OF C8'S TO C10'S)

CAS: 64742-95-6

Fraction By Weight: 1.197%

BUTYL ACETATE SOLVENT

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1.194%

OSHA PEL 150 PPM/STEL 200 PPM

ACGIH TLV: 150 PPM/STEL 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HEXAMETHYLENE DIISOCYANATE MONOMER (SARA 313)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.036%

OSHA PEL 0.005 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

VM&P NAPHTHA SOLVENT

CAS: 8030-30-6

RTECS: DE3030000

Fraction By Weight: 5.025%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

XYLENE (SARA 313)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 2.602%

OSHA PEL 100 PPM/STEL 150 PPM

ACGIH TLV: 100 PPM/STEL 150 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 0.752%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHRONIC: PERMANENT
BRAIN/NS/LIVER/KIDNEY/LUNG DAMAGE. RESP SENSITIZATION. SKIN:
RED/RASH/SCALING/BLISTER/SESITIZATION. ACUTE: INHAL: RESP TRACT
MUCOUS MEMBRANE IRRIT. BRONCHITIS/BRONCHIAL SPASM/PULMON ARY
EDEMA/CHEMICAL OR HYPERSENSITIVE PNEUMONITIS/THROAT DRYNESS/CHEST
TIGHTNESS/HEADACHE/NAUSEA/FATIGUE/APPETITE LOSS.*
Explanation of Carcinogenicity:IARC HAS LISTED SILICA AS A "PROBABLE
HUMAN CARCINOGEN", AND CARBON BLACK AS A POSSIBLE HUMAN CARCINOGEN.
Effects of Overexposure:*SKIN: IRRIT, RED, RASH, SWELL, SCALING,
BLISTER, SENSITIZATION, DEFATTING, DERMATITIS. EYE: IRRIT, TEAR,
RED, SWELL, STINGING SENSTION, CORNEAL DAMAGE, INGEST:
IRRIT/CORROSION TO MOUTH, STOMACH, DIGE STIVE TRACT (SORE THROAT,
ABDOMINAL PAIN, NAUSEA, VOMIT, DIARRHEA, CHEMICAL PNEUMONITIS).
Medical Cond Aggravated by Exposure:SKIN ALLERGIES AND EXEMA, ASTHMA &
OTHER RESPIRATORY AILMENTS, CHEMICAL SENSITIZATION.

First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BREATHING. CALL DR. EYES:
FLUSH IMMED W/LUKE WARM RUNNING WATER >15 MIN, LIFT LIDS. GET MED
AID. SKIN: REMOVE CONTAM CLOTHES/WASH BEFORE REUSE. USE SAFETY
SHOWER (W ASH W/SOAP/WATER). GET MED AID. INGEST:CALL DR IMMED.
DON'T INDUCE VOMITING.

Flash Point Method:TCC
Flash Point:54.0F,12.2C
Autoignition Temp:Autoignition Temp Text:450F
Lower Limits:0.9
Upper Limits:8.2
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT W/SCBA. DURING A
FIRE, IRRITATING & HIGHLY TOXIC GASES & SMOKE ARE PRESENT FROM THE
DECOMPOSITION/COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE W/HEAT OR BURST
WHEN CONTAMINATED W/H20 (CO2 RELEASED). DON'T APPLY TO HOT
SURFACES, WELD, CUT, OR TORCH DRUM.

Spill Release Procedures:EVAC AREA. REMOVE IGNITS. VENT AREA. USE
APPROP PROT EQUIPMENT. AVOID BREATHING VAPORS/SKIN CONTACT.
DIKE/COVER W/INERT ABSORBENT. ADD DECONTAMINANT, ALLOW TO REACT >10
MIN. CONTAINERIZE, ADD MORE DEC ONTAMINANT. COVER LOSELY FOR 24-48
HRS.
Neutralizing Agent:3-8% CONCENTRATED AMMONIA/2% DETERGENT/90-95% H2O OR
TERGITOL 20%/WATER 80%.

Handling and Storage Precautions:DON'T STORE >120F OR <32F. STORE LRG
AMTS IN BUILDINGS DESIGNED TO COMPLY W/OSHA 1910.106. KEEP AWAY
FROM ALL HEAT/MOISTURE. KEEP TIGHTLY CLOSED.
Other Precautions:DON'T INGEST. GROUND WHEN POURING. AVOID POURING
LIQUID IN EXCESS OF FEW INCHES. VENT, USE PROPER RESP EQUIP. CNTNRS
RETAIN RESIDUE AND EXPLOSIVE VAPORS. PROTECT FROM MOISTURE, IF
MOISTURE ENTERS CONT AINER PRESSURE CAN BUILD UP.

Respiratory Protection:AIRLINE RESPIRATORS UNLESS AIR SAMPLING SHOWS
EXPOSURE BELOW OSHA LIMITS. IF BELOW LIMITS USE CHEMICAL CARTRIDGE
RESPIRATORS OR AIRLINE RESPIRATORS.
Ventilation:LOCAL EXHAUST VENTILATION TO KEEP AIR CONTAMINANT
CONCENTRATION BELOW LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GLASSES, FULL-FACE SHIELD
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN
CONTACT AT A MINIMUM.
Work Hygienic Practices:REMOVE & WASH CONTAM CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR SMOKING.
Supplemental Safety and Health
MORE INFORMATION ON FILE.

Boiling Pt:B.P. Text:244 TO 418F
Melt/Freeze Pt:M.P/F.P Text:NOT AVAIL.
Vapor Pres:15.0
Vapor Density:> AIR
Spec Gravity:1.20
pH:NA
VOC Grams/Liter:3.49
Viscosity:65-68 KU
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS, BASES, METAL COMPLEXES, OTHER
ACTIVE MATERIALS OR WATER.
Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, HYDROGEN
CYANIDE, HEXAMETHYLENE DIISOCYANATE, CHLORINE. HYDROGEN CHLORIDE

Waste Disposal Methods:ACCORDING TO GOVERNMENT REGS. DECONTAMINATE
CONTAINERS BEFORE DISPOSAL.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.